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Utilization of phosphogypsum to synthesize α-hemihydrate gypsum …

Phosphogypsum (PG) is a kind of industrial solid waste with high impurity content and low utilization rate. In this study, α-hemihydrate gypsum (α-HH) was synthesized from PG in H 3 PO 4 –H 2 O solution (wet-process phosphoric acid solution and phosphoric acid solution) under atmospheric pressure. The crystal morphology of α …

Understanding gypsum in 3 diagrams

There are three main diagrams that can help us understand this cycle in detail. The first describes the process of water leaving the structure of gypsum to form …

Calcium sulphate hemihydrate hydration leading to gypsum

The three different stages, observed in Fig. 11, correspond to the hemihydrate dissolution, the gypsum nucleation and the gypsum growth. The first …

Mechanism and kinetics of gypsum–anhydrite

Contrary to the gypsum behavior at 90 °C, in the experiments performed at elevated temperatures inside the autoclave, the transformation process proceeded faster, and a different transformation mechanism was observed.In the experiments performed at 150 °C, more than 90% of gypsum transformed to hemihydrate after 2 h retention time, …

The kinetics of the precipitation of gypsum, CaSO4·2H2O

A way to circumvent this phenomenon is to dissolve calcium sulfate hemihydrate (CaSO 4 ·1/2H 2 O), which is more soluble than the dihydarte, and can initiate the gypsum precipitation instantly, as its surface provides a good nucleation and growth site for gypsum [29, 30]. However, during these experiments the dissolution and …

The anhydrous calcium sulphate is called.

The anhydrous calcium sulphate is called Anhydrite. [CaS{O_4}] is anhydrous state or anhydrite. Thus option (B) is the correct answer. Note: If the heating is at a higher temperature, gypsum loses all its water and becomes anhydrous calcium sulfate, ([CaS{O_4}]). Calcium sulphate is majorly used in the manufacturing of plaster …

Preparation of α-High Strength Gypsum from Flue Gas …

The synthesis of α-calcium sulfate hemihydrate (α-CSH) from flue gas desulfurization (FGD) gypsum is a good way to realize the comprehensive utilization of FGD gypsum.To obtain α-CSH with the satisfactory performances, a facile hydrothermal-aging pretreatment process for FGD gypsum raw materials was proposed, where FGD …

Gypsum Products

For instance, the so-called Keene's cement is (ASTM C11 standard) "an anhydrous gypsum plaster characterized by a low mixing water requirement and special setting properties, primarily used with lime to produce hard, dense finish coats." The mixture of hemihydrate gypsum powder with water forms a slurry or paste that will dry and set …

Preparation of hemihydrate gypsum with controllable …

DOI: 10.1016/j.jcrysgro.2021.126360 Corpus ID: 241731164; Preparation of hemihydrate gypsum with controllable morphology in Glycerol-NaCl-Water solutions with maleic acid @article{Chen2021PreparationOH, title={Preparation of hemihydrate gypsum with controllable morphology in Glycerol-NaCl-Water solutions with maleic acid}, …

What is the Difference Between Gypsum and Plaster of Paris

The difference between Gypsum and plaster of Paris is their water content. Gypsum has two water molecules per calcium sulfate molecule, whereas plaster of Paris is its dehydrated form with only half a water molecule. ... The resulting product is plaster of Paris, with the chemical formula CaSO4 • ½ H 2 O (calcium sulfate hemihydrate). This ...

Gypsum vs. Plaster of Paris: What's the Difference?

Gypsum is a mineral (calcium sulfate dihydrate) used in construction; Plaster of Paris is a quick-setting gypsum product used in mold making and casting. Key Differences Gypsum, naturally occurring as a mineral, is widely used in the construction industry for drywall and plaster products.

Difference Between Gypsum and Anhydrite

Difference Between Gypsum and Anhydrite Gypsum vs Anhydrite Gypsum, also called hydrated calcium sulphate (CaSO4 · 2H2O) and anhydrite (CaSO4), also called hydrous calcium sulphate are the major minerals in the sedimentary rocks of rock gypsum and rock anhydrite respectively. Gypsum consists of calcium, sulfur and …

Preparation of gypsum with high purity and whiteness from …

The sulfuric acid slurry containing anhydrous gypsum in the lower layer was vacuum-filtered, washed with deionized water, and dried in an oven at 60 °C for 4 h to obtain high-quality PPG.

Gypsum on heating gives…

Gypsum on heating at 200 0 C gives anhydrous calcium sulphate ( C a S O 4) which is also known as dead burnt plaster. On very strong heating, gypsum ... Calcium sulphate, C a S O 4 is a white crystalline substance. Gypsum is a mineral or natural substance that is hydrate of calcium sulphate. 1.032 g sample of gypsum contains 0.816 g C a S O 4 ...

What is the Difference Between Alpha and Beta Hemihydrate

The difference between alpha and beta hemihydrate is their solubility. Alpha hemihydrate is more soluble and sets faster than the beta form. EXPLORE. Travel & Tour; Education; Language; ... The process of converting gypsum into alpha hemihydrate involves heating gypsum at a specific temperature to remove water molecules, resulting …

On the Solubilities of Anhydrite and Gypsum | SpringerLink

The current paper presents a thermodynamic model for the individual assessment of anhydrite and gypsum solubilities by additionally considering the partial …

Calcium sulphate hemihydrate hydration leading to gypsum

DOI: 10.1016/J.PCRYSGROW.2007.01.002 Corpus ID: 96747728; Calcium sulphate hemihydrate hydration leading to gypsum crystallization @article{Singh2007CalciumSH, title={Calcium sulphate hemihydrate hydration leading to gypsum crystallization}, author={Nakshatra Bahadur Singh and Bernhard Middendorf}, journal={Progress in …

Preparation of α-calcium sulfate hemihydrate from …

gypsum, flue gas desulfurization (FGD) gypsum and phosphogypsum (PG) have the largest output. FGD gypsum originates from the flue gas desulfurization installations by sorption of SO 2 in power stations. For example, in the wet-lime desulfurization method, the sorption reaction occurs via the reaction formulas (1, 2) (Roszczynialski et al., 1996a).

Materials | Free Full-Text | Experimental Study and …

Flue-gas desulphurization (FGD) gypsum is a highly prevalent industrial by-product worldwide, which can be an excellent alternative to natural gypsum due to its high content of CaSO4·2H2O. The preparation of α-calcium sulfate hemihydrate is a high-value pathway for the efficient use of FGD gypsum. Here, a dynamic method, or an improved …

Dehydration Pathways of Gypsum and the …

The dehydration products of gypsum under different temperature and water vapor pressure were investigated by thermodynamic theory. Additionally, the rehydration mechanism of soluble anhydrite was …

Hemihydrate

Sustainability of gypsum products as a construction material. N. Lushnikova, L. Dvorkin, in Sustainability of Construction Materials (Second Edition), 2016 β-Hemihydrate binder. β-Hemihydrate (also known as plaster of Paris) is the most commonly used gypsum binder in construction.It is produced in an apparatus connected to air. Different equipment is …

Calcium Sulphate Hemihydrate and the Anhydrites. I.

several forms of calcium sulphate. The dihydrated salt (gypsum, selenite) and the orthorhombic anhydrous salt (anhydrite) have long been known as common minerals and their chemical and crystallographic characters are well established. About the hemihydrate (plaster of Paris) and the active, hard-setting anhydrous modification (soluble anhydrite),

Effect of Soluble Phosphorus on the Mechanical Properties …

Preparation of α-hemihydrate gypsum crystal is an approach for utilization of phosphogypsum (PG), but the soluble phosphorus impurities in PG have a crucial influence on the performance of α-hemihydrate gypsum. In this article, different forms of soluble phosphorus (H3PO4, H2PO4− and HPO42−) on the setting time and mechanical …

Calcium sulfate | CaSO4 | CID 24497

Gypsum is the dihydrate form and Plaster of Paris is the hemihydrate form. [NIOSH] Used in cement and paper filler (insoluble anhydrite), in a drying agent (soluble anhydrite), in wall plaster and wallboard …

Gypsum hydration: A theoretical and experimental study

The crystallization kinetics of gypsum from a dense suspension of calcium sulfate hemihydrate (weight ratio water/hemihydrate = 20) are followed by a conductimetric method. All stages of the ...

Hydration characteristics and mechanism analysis of β …

However, the comparative study of commercial hemihydrates is rarely reported, not mention the difference in hydration characteristic. The purpose of this search was to understand the hydration of calcium sulfate hemihydrate to gypsum deeply. ESEM was used to observe the dissolution of hemihydrate clearly and continuously.

Gypsum and Anhydrite | Rock & Gem Magazine

The difference is that gypsum (CaSO 4 ·2H 2 O) is a hydrous mineral with two attached molecules of water. Anhydrite, as its name implies, is an anhydrous mineral with no attached water molecules (CaSO 4). Gypsum and anhydrite are textbook examples of how attached water molecules, called "water of hydration", can affect such …

Anhydrite and gypsum

Anhydrite (CaSO 4) and gypsum (CaSO 4 ·2H 2 O) are the two most abundant minerals of ancient marine evaporite deposits and are also common in non-marine evaporite deposits. Sedimentary gypsum forms by direct precipitation out of evaporating seawater under arid climatic conditions in hydrologically restricted marine …

Calcium sulfate | CaSO4 | CID 24497

Gypsum is the dihydrate form and Plaster of Paris is the hemihydrate form. [NIOSH] Used in cement and paper filler (insoluble anhydrite), in a drying agent (soluble anhydrite), in wall plaster and wallboard (hemihydrate), and in soil treatment, Plaster of Paris, Portland cement, water clarification, animal feed, and calcium supplements in food (dihydrate …

Formation of α-Hemihydrate Inside of a Gypsum …

Gypsum (calcium sulfate dihydrate) is one of the most used inorganic binding materials in the world. During calcination, calcium sulfate subhydrates are formed and, for technical reasons, are mixed with water …